Pre-concentration and separation of heavy metal ions by chemically modified waste paper gel

Iminodiacetic acid was immobilized on waste paper by chemical modification in order to develop a new type of adsorption gel for heavy metal ions. Adsorption behavior of the gel was investigated for a number of metal ions, specifically Cu(II), Pb(II), Fe(III), Ni(II), Cd(II), and Co(II) at acidic pH. From batch adsorption tests, the order of selectivity was found to be as follows: Cu(II)  Fe(III) > Pb(II) > Ni(II)  Co(II) > Cd(II). Column tests were carried out for pairs of metal ions to understand the separation and pre-concentration behavior of the gel. It was found that mutual separation of Ni(II) from Co(II) and that of Pb(II) from Cd(II) can be achieved at pH 3. Similarly, selective separation of Cu(II) from Cu(II)–Fe(III) and Cu(II)–Pb(II) mixtures at pH 1.5 and 2, respectively, was observed by using this new adsorption gel. In all cases, almost complete recovery of the adsorbed metal was confirmed by elution tests with HCl.     

Spatial cost efficiency in waste paper handling: the case of corrugated board in Sweden

This paper analyzes the spatial cost efficiency of the Swedish legislation regarding waste disposal handling. We focus on the case of corrugated board and recognize that the different counties in Sweden possess different economic prerequisites in terms of waste paper recovery and utilization potential. We employ data for six corrugated board mills and 20 counties and a non-linear programming model to identify the least cost strategy for reaching the politically specified recycling target of a 65% recovery rate for corrugated board. That is, the total costs of recovering a minimum of 65% in each county are calculated and compared with the case when the country as a whole recovers 65% of all old corrugated board is collected but there exist no uniform target for each county. The conclusion is that from an efficiency point of view the recovery efforts should be concentrated to the highly populated and urbanized counties, and not be uniformly divided throughout the country. In the base case, the results suggest that the cost efficient county-specific recovery rates should range from 51 to 72%.     

雨天硫酸盐化速率样品扩散分析

选择采样期不同降雨天数的碱片，测定余边的硫酸盐化速率含量，其结果为：采样期全月无雨时，余边上的硫酸盐均未检出；半月以上至全月有雨时检出率为１００％，检出量占样品量的２．７０～１５．９５％。经扩散试验，查清了余边上的硫酸盐主要是有效面积上采集的样品的扩散，并提出了相应的修正方法。     

亚铵法制浆造纸厂中段废水处理技术分析研究

通过对采用两级气浮做预处理 ,生物硫化床串联接触氧化做深度处理的治理技术的分析研究 ,结合废水处理工程实例 ,说明了用两级串联气浮 +硫化床 +接触氧化工艺处理造纸中段水技术切实可靠 ,该治理工艺对处理亚铵法麦草制浆造纸中段废水有较强的针对性和可行性。     

厌氧-混凝工艺处理造纸厂终端废水试验研究

本文报告了用厌氧 -混凝工艺处理造纸厂终端废水的实验情况 ,在最佳实验条件下 ,废水从CODcr80 6 . 7m g/ L、BOD52 10 . 5 m g/ L、SS2 15 . 7m g/ L、OD4 650 . 35 0降至 CODcr6 1. 5 m g/ L、BOD52 7. 4m g/ L、SS17.3mg/ L、OD4 650 .0 11。实验结果表明对造纸厂终端废水的治理 ,本工艺是很有实用价值的一种方法     

Analysis of the hydrocyclone stock cleaning process for wasted fibre in a paper mill

The main objective of this project was to evaluate the possibility of reducing the quantity of fibre wasted at one of many hydrocyclone (centrifugal) cleaning processes in a paper mill. It was found that the application of elutriation water to both the tertiary and quaternary cleaners was essential to minimise the fibre discharged to the sewer, and the pressure of this elutriation water had a dramatic effect of reducing the fibre wastage. Accordingly, it has been shown that 150–160 kPa as the optimum pressure range to apply elutriation water to minimise the product grade fibre wasted whilst sending undesired shive fibre to the sewer. Also, monitoring of the press uhle box wastewater revealed that the paper mill has the potential to make substantial cost savings by reducing the waste stream. Further investigation is necessary to determine the types of fibre that are being wasted, and the viability of a screen to recycle the wasted fibre to the process. However, these fibres may be unsuitable to reuse in the process and alternative uses must be found.     

造纸行业的清洁生产示范

文章概述了我国造纸行业清洁生产示范项目审计的成果，从环境、经济及清洁生产方案类型等角度对企业推行清洁生产进行了初步分析，提出了存在的主要问题，并就进一步推动造纸行业的清洁生产提出了建议。     

造纸废水综合治理技术的应用研究

采用“酸化 物化 生化”组合工艺并辅以芦苇湿地处理系统对造纸废水进行综合治理。通过优化工艺条件 ,逐级削减污染负荷 ,使废水排放达到国家标准     

Design of a representative and cost-effective sampling programs for industrial wastewater with examples from bleached kraft pulp and paper mills

The diagram constructed for selection of sampling methods indicates that, for a systematic error, E ≤ 13%, grab sampling (GS) may be used to characterize effluents with variation coefficient of flow ≤ 120% and of contaminant concentrations ≤ 10%. For the whole studied range of variation coefficient of contaminant concentrations (2–82%), time-proportional compositing (TC) method may be applied with E ≤ 10% for effluents characterized by variation coefficients in flow < 90%. The more complicated flow-proportional compositing (FC) method is required only for effluents with larger variation coefficients or to produce more precise results. The diagram constructed for selection of sampling frequencies indicates that sequential sampling at intervals of approximately 60 min may be applied with E ≤ 10% for effluents characterized by variation coefficients ≤ 30%. Practical application of the diagrams, constructed using normal series, was checked against monitoring data from two pulp and paper mills in Vietnam. The two diagrams provided results on sampling methods and frequencies in good agreement with those obtained from actual monitoring data with percentages of agreement cases of 80 and 75%, respectively. The approach was applied in design of a monitoring program at the Bai Bang integrated pulp and paper mill in Vietnam.     

废纸造纸工业节水零排放技术

本文介绍了废纸造纸零排放技术的意义、零排放循环水处理需要解决的问题及工程实践情况。